You can buy your samples with a "vienna harddrive" for an additional €95.
The Vienna Hard Drive is an external 1 TB USB drive that contains the library installation files (*.cab files) for all of the existing Vienna Instruments Collections. Instead of downloading the sample database of the products you’re purchasing you may opt for additional physical delivery. Still, all of the products you’ve purchased will always remain available for download at MyDOWNLOADS. The Vienna Hard Drive does not include any Serial Numbers.
Same goes for software but on a USB stick for €20.
The Vienna Software USB Stick is a 32 GB flash drive that contains all existing Vienna Software installers (including Vienna MIR RoomPacks). Instead of downloading the installers of the products you’re purchasing you may opt for additional physical delivery. It does not include any Serial Numbers.
And trust me, you wouldn't want to buy it on CD's :P