The Fireface has some sweet features that the MOTU's don't have that make it more "pro". Much better clocking, converters, ability to change buffers on the fly, without relaunching, etc. Not to mention, they sound so much better - IMHO. I was just going through my options for an interface, when I thought my multiface was dead, and the Fireface came out on top, hands down. Now, depending on what program you are using - and prefernce to your ears, the Apogee Ensemble is sweet if you are using Logic - lots of integrated control.
RME doesn't have a PCI-e card - unfortunately, but the Fireface is FW800 and, reportedly, the latency is great.
RME doesn't have a PCI-e card - unfortunately, but the Fireface is FW800 and, reportedly, the latency is great.