Andreas, I'm not exactly sure what you meant in you post above by "not identical" and "results in slightly different curves". Am I to understand that the individual Master Volume fader and the individual Expression fader each have a unique 'transfer function' or 'calibration' - call it what you will - in terms of attenuation dB versus CCvalue? I think that's what you've asserted but would you kindly clarify?
I promise you I'm not asking merely pedantically; I do have a real and practical need to know.
[UPDATE]
Well I've just done many more test measurements. And now my question is different. Now the issue is quantitative rather than qualitative.
Yes I have now discovered what a few spot checks didn't reveal previously: there are indeed numerous small differences in calibration between the two faders. I was caught napping by this unexpected circumstance.
And yet strangely, many CCvals give exactly the same attenuation dB level in both faders - within my meter's resolution of 0.01dB at least. The differences seem to be just peppered around - I haven't yet come up with any plausible purpose..
I've found that only 4 of these differences come anywhere near to being possibly significant (0,58, 0.61 0.70, and 0.76 dB, all at below -30dB of attenuation). The other differences are less than 0.4 dB, many of these being so small that they're impossible for me to distinguish from experimental error. I don't imagine that any of them are likely to have any noticeable impact on gain-staging and mixing in actual practice. It's said that most people can't distinguish level changes of less than about 1 dB. All of these differences are less than 1 dB; all but a few being far less.
So my question, Andreas, is changed.
Why is there this strange peppering of insignificantly small 'calibration' or 'transfer function' differences between these two main faders? And why your caution? Why do we need to be mindful of which way around they are connected? Cannot their respective attenuation dB levels be simply summed in order to know their combined attenuation?
I don't actually mind the presence of these small differences because I don't see how they can significantly affect any of our usual, practical level-adjustment activities. But is there perhaps some other factor, maybe some hidden conditional attenuation mechanism operating between these 2 faders that prevents their combined use from being straightforward and virtually 'ambidextrous'?