In the Directory Manager you will have to add the folders, where your VSL content is located. 100 SpecialEdition sounds right.
With "VSL-SE" I guess you are talking about a Vienna Instruments player (VI). You should have the same presets/matrices/patches available in Vienna Ensemble (VE) and VI.
If you click on Instrument 1 in VE, you see a list of all found licenses on the left side. Does Special Edition appear there? If yes, and you still can't find any presets/matrices/patches, you will have to add the content to your Directory Manager.
Vienna Symphonic Library